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Did a little research and I'm pretty sure that "frozen" is the same as "matte". Its just what BMW calls it because they are trying to be all fancy.

Since June 2010, certain BMW models are painted with “Frozen” or “Matte” exterior paints. With the launch of the all-new BMW 6 Series Gran Coupe, a Frozen Paint was released for the first time as a factory option.

This two-stage paint process consists of a color base coat, followed by a specially formulated matte finish clear coat.
 
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